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Optimum pH for
nutrient solutions
 

Failure to understand and apply the following is one of the key reasons for nutrient failure.


For nutrients to remain dissolved and therefore available for uptake by roots, it is critical to maintain the pH between 5.0 and 6.0 - with an absolute maximum of 6.5 (Fig 1.2).
High pH values (i.e. above 6.0) are to be avoided more than low values (e.g. pH 4.5 to 5.0). The effect of low pH’s upon the stability of nutrients is relatively insignificant.
The precise pH at which precipitation of macro-nutrients starts is determined by the combined concentrations of calcium and sulfate. Except for fertilizers ‘low’ in calcium and sulfate this problem commonly occurs at ~pH 6.5 where the net* EC is ~2.5 mS, or ~pH 7.0 for 1.5 mS solutions. Hence, to avoid precipitation, higher nutrient concentrations generally must be held at lower pH values.

*Assumes make-up water has nil EC.

In spite of this precipitation problem, some references advocate pH values well above 6.5 for some plant varieties - conditions which risk depleted concentrations of the above mentioned elements.  This is incorrectly justified by quoting the chart in Fig 1.1 as proof.  Before following such advice you may wish to test for yourself whether or not this problem will occur with your water and nutrient mixture by performing the "Jar test". 

 

pH recommendation of 6.2 - 6.3?

Although this is a popular recommendation, it has no scientific basis. It appears to have gained ‘mythological’ status from the early days of hydroponics when the only cheap means of measuring pH was the common ‘bromothymol blue’ pH indicator used for testing fish tank water. Interestingly, the lowest pH value able to be determined by that indicator is about 6.2. Hence, this value has unfortunately become an entrenched recommendation in some sections of the hydroponic industry.

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Related topics:

"pH Control":

What is pH? | Optimum pH for nutrient solutions | Adjusting nutrient pH | Handy hints for adjusting pH |

The pH value of raw water is meaningless! | Measuring pH with 'indicators' | Measuring pH with pH Meters |

Calibrating pH meters | Common mistakes with pH meters | pH meter maintenance | pH meter accuracy | Buying a pH meter

 

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This page was last updated 02 March, 2010